PROPERTIES OF (XCF3CH2OH + (1-X)H2O) AT TEMPERATURES FROM 310-K TO 420-K .1. BUBBLE PRESSURES AND SATURATED-LIQUID DENSITIES

被引：9

作者：

KABATA, Y ^{[1
]}

TAKADA, M ^{[1
]}

SONOBE, R ^{[1
]}

SUGIURA, I ^{[1
]}

UEMATSU, M ^{[1
]}

机构：

[1] KEIO UNIV,DEPT MECH ENGN,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1993年 / 25卷 / 05期

关键词：

D O I：

10.1006/jcht.1993.1061

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Bubble pressures and saturated-liquid densities for {xCF3CH2OH + (1-x)H2O} with x = 0.01935, 0.05072, 0.1510, 0.3013, 0.5011, 0.6533, and 0.8513 have been measured at temperatures from 310 K to 420 K. The experimental uncertainties of temperature T, mole fraction x, bubble pressure pb, and saturated-liquid density ρ1 have been estimated to be no worse than ±3 mK, ±0.0008, ±0.9 kPa, and ±0.0010·ρ1, respectively. The results show that CF3CH2OH is miscible with H2O at all compositions. The bubble pressures indicate positive deviations from Raoult’s law at all temperatures measured and that the relative deviations increase with decreasing temperature. © 1993 Academic Press Ltd.

引用

页码：649 / 652

页数：4

共 7 条

[1] THERMODYNAMIC BEHAVIOR OF MIXTURES CONTAINING FLUOROALCOHOLS .1. (WATER + 2,2,2-TRIFLUOROETHANOL) [J].