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RAMAN AND INFRARED-SPECTRA IN ORGANIC LAYER CRYSTALS OF SQUARIC ACID

被引：16
作者：
NAKASHIMA, S
AZIZA, A
LEPOSTOLLEC, M
BALKANSKI, M
机构：
[1] UNIV PARIS 06, CNRS, PHYS SOLIDES LAB, F-75230 PARIS 05, FRANCE
[2] UNIV PARIS 06, DEPT RECH PHYS, F-75230 PARIS 05, FRANCE
来源：
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 1979年 / 94卷 / 02期
关键词：
D O I：
10.1002/pssb.2220940224
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The Raman spectra of squaric acid and its deuterated derivative are measured for temperatures from 77 to 450 K covering both ordered and disordered phases. Infrared absorption spectra are investigated for thin films of the single crystals and compared with the Raman spectra. It is found that the vibrational Davydov splitting due to the interlayer interaction is large for the external modes, while it is small for the internal modes of the squarie molecule. This behavior is explained by the model that the interlayer interaction acts between the hydrogen bonds of adjacent layers and is localized in the region near the hydrogen bonds. The temperature dependence of the frequencies and the linewidths is discussed in relation to the phase transition mechanism. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA
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收藏
页码：529 / 539
页数：11
相关论文
共 18 条
[1]   INFRARED AND RAMAN SPECTRA OF CRYSTALLINE SQUARIC ACID [J].
BAGLIN, FG ;
ROSE, CB .
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1970, A 26 (12) :2293-&
[2]   ALPHA-BETA TRANSITION IN QUARTZ - CLASSICAL VERSUS CRITICAL BEHAVIOR [J].
BANDA, EJKB ;
CRAVEN, RA ;
PARKS, RD ;
HORN, PM ;
BLUME, M .
SOLID STATE COMMUNICATIONS, 1975, 17 (01) :11-14
[3]   VIBRATIONAL STUDY OF SQUARIC ACID [J].
BOUGEARD, D ;
NOVAK, A .
SOLID STATE COMMUNICATIONS, 1978, 27 (04) :453-457
[4]   DIKETOCYCLOBUTENEDIOL [J].
COHEN, S ;
LACHER, JR ;
PARK, JD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (13) :3480-3480
[5]   NEW AROMATIC ANIONS .4. VIBRATIONAL SPECTRA AND FORCE CONSTANTS FOR C404-2 AND C505-2 [J].
ITO, M ;
WEST, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (17) :2580-&
[6]   RAMAN STUDY OF SQUARIC ACID [J].
NAKASHIMA, S ;
BALKANSKI, M .
SOLID STATE COMMUNICATIONS, 1976, 19 (12) :1225-1228
[7]  
Novak A., 1974, STRUCT BOND, V18, P177, DOI [10.1007/BFb0116438, DOI 10.1007/BFB0116438]
[8]   SQUARIC ACID, A 2-DIMENSIONAL HYDROGEN-BONDED MATERIAL WITH A PHASE-TRANSITION [J].
SAMUELSEN, EJ ;
SEMMINGSEN, D .
SOLID STATE COMMUNICATIONS, 1975, 17 (02) :217-219
[9]   CRYSTAL-STRUCTURE OF SQUARIC ACID [J].
SEMMINGS.D .
ACTA CHEMICA SCANDINAVICA, 1973, 27 (10) :3961-3972
[10]   NEUTRON-DIFFRACTION STUDY OF SQUARIC ACID (3,4-DIHYDROXY-3-CYCLOBUTENE-1,2-DIONE) [J].
SEMMINGSEN, D ;
HOLLANDER, FJ ;
KOETZLE, TF .
JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (10) :4405-4412
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