SYNTHESIS OF BETA-SUBSTITUTED PORPHYRINS USING PALLADIUM-CATALYZED REACTIONS

被引：48

作者：

ALI, H ^{[1
]}

VANLIER, JE ^{[1
]}

机构：

[1] UNIV SHERBROOKE,FAC MED,MRC,RADIAT SCI GRP,SHERBROOKE J1H 5N4,PQ,CANADA

来源：

TETRAHEDRON | 1994年 / 50卷 / 41期

基金：

英国医学研究理事会;

关键词：

BETA-HALOGENATED PORPHYRINS; PALLADIUM CATALYZED REACTION; COUPLING REACTION; TERMINAL ACETYLENIC DERIVATIVE;

D O I：

10.1016/S0040-4020(01)89306-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium(II)-catalysed carbon-carbon-coupling reaction (Heck reaction) between a variety of metalated beta-monohalosubstituted porphyrins (2-bromotetraphenylporphyrin, 2-bromo-3,7,8,12,13,17,18-heptaethylporphyrin, and 3(8)monoiodo-deuterporphyrin IX dimethyl ester) and a series of terminally substituted acetylenic derivatives, is reported. A few disubstituted porphyrin analogs were also synthesized using the corresponding beta-dihalogenated porphyrin precursors.

引用

页码：11933 / 11944

页数：12

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