DETERMINING CENTROSYMMETRIC DIMERS BY INFRARED AND RAMAN SPECTROSCOPY

被引:16
作者
ZIFFER, H
LEVIN, IW
机构
[1] National Institute, Arthritis and Metabolic Diseases, National Institutes of Health, Bethesda
关键词
D O I
10.1021/jo01264a065
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Infrared and Raman spectra of cyclobutane photodimers of 2-cyclopentenone, 2-cyclohexenone, 3-methyl-2- cyclohexenone, and isophorone were recorded. A comparison of the vibrational data for the head-to-head and head-to-tail anti species of each of the four sets of dimers has been used, in conjunction with the Mutual Exclusion Rule, to identify the centrosymmetric dimer. © 1969, American Chemical Society. All rights reserved.
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页码:4056 / &
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