MULTIPOINT INTERACTION OF PHOSPHATES WITH PROTONATED PYRIDYLPORPHYRIN - DISCRIMINATION OF MONOALKYL AND DIALKYL PHOSPHATES

被引：12

作者：

AOYAMA, Y ^{[1
]}

NONAKA, S ^{[1
]}

MOTOMURA, T ^{[1
]}

TOI, H ^{[1
]}

OGOSHI, H ^{[1
]}

机构：

[1] KYOTO UNIV, DEPT SYNTHET CHEM, SAKYO KU, KYOTO 606, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 07期

关键词：

D O I：

10.1246/cl.1991.1241

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rigid and unique polyammonium binding site of fully protonated 5,15-bis(2-pyridyl)octaethylporphyrin allows novel discrimination of monoalkyl phosphate vs. dialkylphosphate as well as oxy- and dicarboxylic acids vs. monocarboxylic acid; the former are readily bound with the protonated porphyrin via multi-point interaction, while the latter not.

引用

页码：1241 / 1244

页数：4

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