THE DEMONSTRATION OF THE TRIGONAL TWIST MECHANISM IN [RUH2(CO)(PPH3)3]

被引：25

作者：

BALL, GE

MANN, BE

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NOESY has been used to demonstrate that, unexpectedly, [RuH2(CO)(PPh3)3] undergoes intramolecular ligand exchange, probably via the trigonal twist mechanism; it is shown how heteronuclear coupling in the NOESY experiment can yield valuable mechanistic information.

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页码：561 / 563

页数：3

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