A PARAMETRIC STUDY OF BIMOLECULAR EXCHANGE REACTIONS

被引：8

作者：

BUNKER, DL

CHANG, TS

机构：

[1] Department of Chemistry, University of California, Irvine, CA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 04期

关键词：

D O I：

10.1021/j100724a031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For the reaction A + BC → AB + C, we have constructed a treatment in which the degree of adiabaticity or statisticality of the process may be parametrically varied. Reaction probabilities and product energy distributions have been calculated for K + Cl2, Cs + CH3I, H + Cl2, K + HBr, and H + H2. The form of the theory that best describes these reactions is a semistatistical one, somewhat more closely allied to the statistical treatment of Light than to the adiabatic model of Marcus.

引用

页码：943 / &

共 30 条

[1] ENERGY DISTRIBUTION AMONG REACTION PRODUCTS .2. H+X2 AND X+HY [J].