SUPERCOOLING OF POLYDIMETHYLSILOXANE

被引：36

作者：

HELMER, JD

POLMANTEER, KE

机构：

[1] Chemical Research Department, Dow Corning Corporation, Midland, Michigan

[2] Battelle Memorial Inst, Columbus, Ohio

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1969年 / 13卷 / 10期

关键词：

D O I：

10.1002/app.1969.070131008

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This study was undertaken to determine the quenching rates necessary to supercool polydimethylsiloxane. A technique was developed that allowed controlled quenching rates up to 52°C/see and a modified DTA apparatus was used to obtain thermograms during the warm‐up cycle. No supercooling was observed for a cooling rate of 1.6°C/sec; 56% supercooling was found for a 9.6°C/sec cooling rate; 65% for 10.6°C/sec and 85% for a 52°C/sec cooling rate. Evidence was also presented showing that the crystals in polydimethylsiloxane consist of two forms. Copyright © 1969 John Wiley & Sons, Inc.

引用

页码：2113 / +

页数：1

共 11 条

[1]

BACON K, 1964, NEWER METHODS POLYME, P391

[2]

BACON K, 1964, NEWER METHODS POLYME, P395

[3]

BACON K, 1964, NEWER METHODS POLYME, P388

[4]

FISCHER DJ, 1961, J APPL POLYM SCI, V16, P436

[5]

KINGDON F, 1962, HERCULES CHEMIST, P5

[6] BEHAVIOR OF SILASTIC ON AGING [J].

KONKLE, GM ;

SELFRIDGE, RR ;

SERVAIS, PC .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1947, 39 (11) :1410-1413

[7] CRYSTALLINITY AND ORIENTATION IN SILICONE RUBBER .1. X-RAY STUDIES [J].

OHLBERG, SM ;

ALEXANDER, LE ;

WARRICK, EL .

JOURNAL OF POLYMER SCIENCE, 1958, 27 (115) :1-17

[8]

Polmanteer K., 1959, J APPL POLYM SCI, V1, P3

[9] LOW TEMPERATURE BEHAVIOR OF SILICONE AND ORGANIC RUBBERS [J].

POLMANTEER, KE ;

SERVAIS, PC ;

KONKLE, GM .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1952, 44 (07) :1576-1581

[10] CRYSTALLINITY AND ORIENTATION IN SILICONE RUBBER .2. PHYSICAL MEASUREMENTS [J].

WARRICK, EL .

JOURNAL OF POLYMER SCIENCE, 1958, 27 (115) :19-38

← 1 2 →