THERMAL-STABILITY OF LITHIUM ANODES IN AN AMORPHOUS V2O5/LI BATTERY SYSTEM

被引：8

作者：

ARAKAWA, M ^{[1
]}

NEMOTO, Y ^{[1
]}

TOBISHIMA, S ^{[1
]}

ICHIMURA, M ^{[1
]}

YAMAKI, J ^{[1
]}

机构：

[1] ADV ENERGY TECHNOL INC, BURNABY V5C 4G2, BC, CANADA

来源：

JOURNAL OF POWER SOURCES | 1993年 / 44卷 / 1-3期

关键词：

D O I：

10.1016/0378-7753(93)80197-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Safety is one of the most important factors in the development of lithium cells. The thermal stability of a-V2O5/Li cells is investigated. Vanadium compound deposition on a lithium anode during charge/discharge cycles is observed. Vanadium compounds dissolve electrochemically and are deposited on the anode. The low reactivity of the vanadium deposited lithium anode is observed by calorimetry. Chemical-state analysis and morphological investigation of the lithium anode suggest that the improvement in stability is primarily due to the passivation film.

引用

页码：517 / 520

页数：4

共 6 条

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HIRAI, T
YAMAKI, J
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[2] ARAKAWA M, 1992, 6TH INT M LITH BATT
[3] LAMMAN FC, 1992, 6TH INT M LITH BATT
[4] V2O5-P2O5 GLASSES AS CATHODE FOR LITHIUM SECONDARY BATTERY
SAKURAI, Y
YAMAKI, J
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (02) : 512 - 513
[5] VONSACKEN U, 1990, 178TH ECS M SEATTL, P87
[6] WILKINSON DP, 1990, 178TH ECS M SEATTL, P85

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