PHENOL OXIDATION AND BIOSYNTHESIS .19. ON ROLE OF QUATERNARY METHO-SALTS IN ALKALOID BIOSYNTHESIS

被引：7

作者：

BARTON, DHR

BOAR, RB

WIDDOWSON, DA

DEULOFEU, V

ALBONICO, SM

机构：

[1] Facultad de Ciencias Exactas y Naturales, Buenos Aires

[2] Facultad de Farmacia y Bioquimica, Buenos Aires

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 05期

关键词：

D O I：

10.1039/j39690000807

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The incorporation of tritiated (+)-tembetarine chloride (reticuline methochloride) into sinomenine (in Sinomenium acutum) and into protopine (in Dicentra spectabilis) has been determined. By comparison with (+)-reticuline, an established intermediate in the biosynthesis of sinomenine and of protopine, (+)-tembetarine is an inefficient precursor.

引用

页码：807 / +

页数：1

共 13 条

[1]

ALBONICO SM, 1965, LIEBIGS ANN CHEM, V685, P200

[2]

Barton D. H. R., 1957, FESTSCHRIFT A STOLL, P117

[3] PHENOL OXIDATION AND BIOSYNTHESIS .12. STEREOCHEMICAL STUDIES RELATED TO BIOSYNTHESIS OF MORPHINE ALKALOIDS [J].

BARTON, DHR ;

BHAKUNI, DS ;

JAMES, R ;

KIRBY, GW .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (02) :128-&

[4]

BARTON DHR, 1963, P CHEM SOC LONDON, P293

[5] INVESTIGATIONS ON BIOSYNTHESIS OF MORPHINE ALKALOIDS [J].

BARTON, DHR ;

KIRBY, GW ;

STEGLICH, W ;

THOMAS, GM ;

BATTERSBY, AR ;

DOBSON, TA ;

RAMUZ, H .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (APR) :2423-+

[6]

BARTON DHR, 1963, P CHEM SOC LONDON, P203

[7] PHENOL OXIDATION AND BIOSYNTHESIS .17. INVESTIGATIONS ON BIOSYNTHESIS OF SINOMENINE [J].

BARTON, DHR ;

KIRBY, AJ ;

KIRBY, GW .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (08) :929-&

[8] PHENOL OXIDATION AND BIOSYNTHESIS .8. INVESTIGATIONS ON BIOSYNTHESIS OF BERBERINE AND PROTOPINE [J].

BARTON, DHR ;

HESSE, RH ;

KIRBY, GW .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (NOV) :6379-+

[9]

BATTERSBY AR, 1963, P CHEM SOC LONDON, P189

[10] ALKALOID BIOSYNTHESIS .11. STUDIES RELATED TO FORMATION AND OXIDATION OF RETICULINE IN MORPHINE BIOSYNTHESIS [J].

BATTERSBY, AR ;

FOULKES, DM ;

HIRST, M ;

PARRY, GV ;

STAUNTON, J .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1968, (02) :210-+

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