PROPERTIES OF THIONYL CHLORIDE SOLUTIONS (EXTENDED ABSTRACT)

被引：2

作者：

COHEN, R

KIMEL, J

ELSTER, E

PELED, E

EFRIMA, S

机构：

[1] TEL AVIV UNIV, SCH CHEM, IL-69978 TEL AVIV, ISRAEL

[2] BEN GURION UNIV, DEPT CHEM, BEERSHEBA, ISRAEL

来源：

JOURNAL OF POWER SOURCES | 1989年 / 26卷 / 1-2期

关键词：

Alkaline Earth Compounds - Electrolytes--Ionic Conduction - Solutions--Physical Chemistry - Solvents;

D O I：

10.1016/0378-7753(89)80009-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solutions of alkali metal tetrachloroaluminates in thionyl chloride (TC) exhibit very interesting physicochemical properties. They have been studied mainly in connection with the development of the Ca-TC battery. It was recently found that replacing the Ca(AlCl4)2 electrolyte in the Ca-TC battery by either Ba(AlCl4)2 or Sr(AlCl4)2 resulted in a battery with a much longer shelf life. The purpose of this paper was to describe the physicochemical properties of TC solutions of calcium, strontium, and barium tetrachloroaluminates, with emphasis on the effect of SO2 on the solution properties.

引用

页码：5 / 7

页数：3

共 6 条

[1] STORAGE PROPERTIES OF ADVANCED C-SIZE CALCIUM-THIONYL CHLORIDE BATTERIES [J].