DETERMINATION OF SE(IV) IN WATER BY NEUTRON-ACTIVATION ANALYSIS AFTER COPRECIPITATION OF METAL DIBENZYLDITHIOCARBAMATE WITH PHENOLPHTHALEIN

被引：13

作者：

SALEH, AI

WOITTIEZ, JRW

WALS, GD

DAS, HA

机构：

[1] Netherlands Energy Research Foundation, Petten (N. H.), 1755 ZG

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1990年 / 140卷 / 02期

关键词：

D O I：

10.1007/BF02039508

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A neutron activation analysis method for the determination of Se(IV) in natural waters is described. It is based on the coprecipitation of the metal dibenzyldithiocarbamate with phenolphthalein. The precipitate is collected on 0.45 μm membrane filters and selenium is determined by instrumental neutron activation. A Se(IV) radiotracer (75Se, T=120 d) was used to establish optimum conditions and to evaluate the chemical yield. Samples of sea and canal water were analyzed. © 1990 Akadémiai Kiadó.

引用

收藏

页码：357 / 363

页数：7

相关论文

共 18 条

[1] PRECONCENTRATION OF MICROAMOUNTS OF ELEMENTS IN NATURAL-WATERS WITH 8-MERCAPTOQUINOLINE AND BIS(8-QUINOLYL) DISULFIDE FOR THEIR ATOMIC-ABSORPTION DETERMINATION [J].

BANKOVSKY, YA ;

VIRCAVS, MV ;

VEVERIS, OE ;

PELNE, AR ;

VIRCAVA, DK .

TALANTA, 1987, 34 (01) :179-182

[2] DETERMINATION OF HEAVY-METALS IN SEAWATER BY ATOMIC-ABSORPTION SPECTROMETRY AFTER ELECTRODEPOSITION ON PYROLYTIC GRAPHITE-COATED TUBES [J].

BATLEY, GE .

ANALYTICAL CHEMISTRY, 1977, 49 (13) :2031-2035

[3] DETERMINATION OF VERY LOW-LEVELS OF SELENIUM(IV) IN SEA-WATER BY DIFFERENTIAL-PULSE CATHODIC STRIPPING VOLTAMMETRY AFTER EXTRACTION OF THE 3,3'-DIAMINOBENZIDINE PIAZSELENOL [J].

BREYER, P ;

GILBERT, BP .

ANALYTICA CHIMICA ACTA, 1987, 201 :33-41

[4] APDC-MIBK EXTRACTION SYSTEM FOR DETERMINATION OF TRACE ELEMENTS IN SALINE WATERS BY ATOMIC-ABSORPTION SPECTROPHOTOMETRY [J].

BROOKS, RR ;

PRESLEY, BJ ;

KAPLAN, IR .

TALANTA, 1967, 14 (07) :809-&

[5] TRACE-METALS SPECIES IN SEA-WATER .1. REMOVAL OF TRACE-METALS FROM SEA-WATER BY A CHELATING RESIN [J].

FLORENCE, TM ;

BATLEY, GE .

TALANTA, 1976, 23 (03) :179-186

[6]

GENOVA N, 1983, RADIOCHEM RADIOANAL, V58, P27

[7]

GOMISCEK VHS, 1978, ANAL CHIM ACTA, V98, P39

[8] DETERMINATION OF SELENIUM(IV) AND OTHER FORMS OF SELENIUM DISSOLVED IN SEA-WATER BY ANION-EXCHANGE RESIN LOADED WITH SULFONIC-ACID DERIVATIVE OF BISMUTHIOL-II AND HYDRIDE GENERATION ATOMIC-ABSORPTION SPECTROMETRY [J].

ITOH, K ;

CHIKUMA, M ;

NISHIMURA, M ;

TANAKA, T ;

TANAKA, M ;

NAKAYAMA, M ;

TANAKA, H .

FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1989, 333 (02) :102-107

[9] DETERMINATION OF SELENIUM IN WATER SAMPLES FROM ENVIRONMENT [J].

MASSEE, R ;

VANDERSLOOT, HA ;

DAS, HA .

JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1977, 35 (01) :157-165

[10] DETERMINATION OF ARSENIC, MOLYBDENUM, URANIUM, AND VANADIUM IN SEAWATER BY NEUTRON-ACTIVATION ANALYSIS AFTER PRE-CONCENTRATION BY COLLOID FLOTATION [J].

MURTHY, RSS ;

RYAN, DE .

ANALYTICAL CHEMISTRY, 1983, 55 (04) :682-684