SECONDARY ION MASS-SPECTRA OF GOLD SUPER CLUSTERS UP TO 140000 DALTON

被引:24
作者
FELD, H [1 ]
LEUTE, A [1 ]
RADING, D [1 ]
BENNINGHOVEN, A [1 ]
SCHMID, G [1 ]
机构
[1] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,W-4300 ESSEN 1,GERMANY
来源
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS | 1990年 / 17卷 / 01期
关键词
07.75.+h; 35.20.Wg; 36.40.+d;
D O I
10.1007/BF01437501
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The bombardment of a two-shell gold complex (Au55(PPh3)12Cl6) with 10 keV Xe+-ions results in the formation of secondary ion masses up to 140000 u. These are by far the largest secondary ions observed under primary particle bombardment. The detection and identification of these ions with a Time-Of-Flight Secondary Ion Mass Spectrometer (TOF-SIMS) gives important information about the behavior of naked full-shell clusters. Au13 particles, generated from the Au55 cluster, serve as building blocks for a series of super-clusters up to (Au13)55. The results for keV-ion bombardment are compared to those for MeV-ion bombardment. © 1990 Springer-Verlag.
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页码:73 / 76
页数:4
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