THE SYNTHESIS, ELECTROCHEMISTRY AND THERMAL-BEHAVIOR OF SOME MOLYBDENUM MONONITROSYL COMPLEXES INCORPORATING STILBENAMIDE LIGANDS CARRYING LONG-CHAIN ALKOXY SUBSTITUENTS

被引：9

作者：

COE, BJ

JONES, CJ

MCCLEVERTY, JA

BRUCE, DW

机构：

[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

[2] UNIV SHEFFIELD,SHEFFIELD CTR MOLEC MAT,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)87052-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new complexes [Mo(NO)L(X)(NHC6H4CH=CHC6H4OR-4,4')] (R = C6H13, X = Cl, I, OH; R = C8H17 or C12H25 and X = Cl or I) and [Mo(NO)L(NHC6H4 CH=CHC6H4OR-4,4')2] (R=C6H13, C8H17 or C12H25) have been synthesized and characterized by spectroscopic methods. All undergo one-electron reduction processes at potentials ranging from -0.74 to - 1.20 V (vs S.C.E.). These new compounds have also been examined by differential scanning calorimetry and polarizing hot-stage microscopy, but do not exhibit any liquid crystalline mesophases.

引用

页码：45 / 53

页数：9

共 17 条

[1] MONOMETALLIC, HOMO-BIMETALLIC AND HETEROBIMETALLIC COMPLEXES BASED ON REDOX ACTIVE TRIS(3,5-DIMETHYLPYRAZOLYL)BORATO-MOLYBDENUM AND -TUNGSTEN NITROSYLS .4. THE EFFECTS OF LIGATING ATOM TYPE ON THE REDUCTION POTENTIALS OF MONOMETALLIC COMPLEXES [J].