TURCASARIN, THE LARGEST EXPANDED PORPHYRIN TO DATE

被引：138

作者：

SESSLER, JL ^{[1
]}

WEGHORN, SJ ^{[1
]}

LYNCH, V ^{[1
]}

JOHNSON, MR ^{[1
]}

机构：

[1] GEORGE WASHINGTON UNIV, DEPT CHEM, WASHINGTON, DC 20052 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 14期

关键词：

D O I：

10.1002/anie.199415091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

40π‐Electrons and ten pyrrole units are found in macrocycle 1, the largest expanded porphyrin reported thus far. The tetrahydrochloride salt of 1 was characterized in solution and in the solid state. These investigations indicate that the macrocycle exists as a pair of enantiomers whose chirality arises from a twist of the ring. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1509 / 1512

页数：4

共 35 条

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