MOLTEN SODIUM NITRITE-POTASSIUM NITRITE EUTECTIC - REACTIONS OF SOME COMPOUNDS OF LEAD

被引：5

作者：

ALOMER, SS

KERRIDGE, DH

机构：

[1] Department of Chemistry, The University, Southampton

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 03期

关键词：

D O I：

10.1016/0022-1902(79)80132-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of seven lead compounds in molten sodium nitrite-potassium nitrite eutectic have been examined and the temperatures and stoichiometries of the reactions established. The thermal decomposition of lead(II) nitrite is the key reaction; this compound apparently being formed from lead(II) nitrate and chloride by anion exchange and from red lead on removal of lead(II) cations. Lead(IV), as oxide or oxyanion, oxidises nitrite to nitrate, while lead(II) oxide and metallic lead are relatively unreactive. © 1979.

引用

页码：273 / 276

页数：4