ADDITION AND DEPROTONATION IN REACTIONS OF HYDROXIDE ION WITH A BETA-HYDROXYSILANE

被引：5

作者：

ANGELINI, G ^{[1
]}

JOHNSON, CE ^{[1
]}

BRAUMAN, JI ^{[1
]}

机构：

[1] STANFORD UNIV, DEPT CHEM, STANFORD, CA 94305 USA

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1991年 / 109卷

关键词：

D O I：

10.1016/0168-1176(91)85093-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The reaction of hydroxide ion with a beta-hydroxysilane, 2-trimethylsilylmethyl-2-propanol, has been studied in an ion cyclotron resonance Fourier transform mass spectrometer. Using labeled hydroxide, details of deprotonation of the hydroxyl group versus addition to silicon were established. The rate of deprotonation at the hydroxyl group is about one-half the rate of addition to silicon.

引用

页码：1 / 14

页数：14

共 25 条

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