LUMINESCENT UNIDIMENSIONAL ORGANOMETALLIC MATERIALS - STRUCTURAL AND EMISSION PROPERTIES OF THE ([AG(DMB)2](Y))N POLYMERS (DMB = 1,8-DIISOCYANO-PARA-MENTHANE, Y = PF6, BF4, NO3)

被引：36

作者：

PERREAULT, D ^{[1
]}

DROUIN, M ^{[1
]}

MICHEL, A ^{[1
]}

HARVEY, PD ^{[1
]}

机构：

[1] UNIV SHERBROOKE,DEPT CHIM,SHERBROOKE J1K 2R1,QUEBEC,CANADA

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 18期

关键词：

D O I：

10.1021/ic00044a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper describes the preparation and characterization of a new organometallic quasi-unidimensional (1-D) material based upon Ag+ and diisocyano-p-menthane (dmb) with a Ag(dmb)2+ stoichiometry. The X-ray structure reveals a 1-D structure in which the dmb ligands are unidirectionally oriented. The polymers are insulating, exhibiting long Ag+...Ag+ separations (approximately 5 angstrom), and remain intact in solutions. They also are found to be luminescent both in solution and in the solid state.

引用

页码：3688 / 3689

页数：2

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