INTERCALATIVE POLYMERIZATION OF 3-METHYLPYRROLE AND 3,4-DIMETHYLPYRROLE IN THE VOPO4 INTERLAYER SPACE

被引：26

作者：

MATSUBAYASHI, G

NAKAJIMA, H

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 01期

关键词：

D O I：

10.1246/cl.1993.31

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Finely powdered VOPO4.2H2O suspended in an ethanol solution containing 3-methyl- or 3,4-dimethylpyrrole leads to the intercalative polymerization of these pyrrole derivatives through the 2,5-coupling to yield VOPO4.(H2O)1.4.(EtOH)0.2.(MeC4HNH)0.65 and VOPO4.(H2O)1.8.(EtOH)0.2.(Me2C4NH)0.6. The similar treatment Of VOPO4.2H2O with pyrrole affords polypyrrole only on the VOPO4 surface.

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页码：31 / 34

页数：4

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