RESONANCE RAMAN-SPECTRUM OF THE TRANSIENT (SCN)2 FREE-RADICAL ANION

被引：33

作者：

WILBRANDT, R ^{[1
]}

JENSEN, NH ^{[1
]}

PAGSBERG, P ^{[1
]}

SILLESEN, AH ^{[1
]}

HANSEN, KB ^{[1
]}

HESTER, RE ^{[1
]}

机构：

[1] UNIV YORK,DEPT CHEM,YORK Y01 5DD,N YORKSHIRE,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 60卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0009-2614(79)80042-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The resonance Raman spectrum of the transient species (λmax = 475 nm, τ 1 2 = 1.6 μs) formed by pulse radiolysis of aqueous solutions of thiocyanate, SCN2-, is reported. The spectrum is discussed in terms of the previous assignment of this transient to the radical anion, (SCN)- 2. The observed vibrational frequencies of the radical anion are consistent with substantial weakening of the SS and the CN bonds are compared with neutral thiocyanogen. © 1979.

引用

页码：315 / 319

页数：5

共 27 条

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