RARE EARTH-IRON(COBALT, NICKEL)-SILICON COMPOUNDS

被引:31
作者
MAYER, I
TASSA, M
机构
[1] Department of Inorganic and Analytical Chemistry, The Hebrew University
来源
JOURNAL OF THE LESS-COMMON METALS | 1969年 / 19卷 / 03期
关键词
D O I
10.1016/0022-5088(69)90092-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
MSi1.6(Fe, Co, Ni)0.4 compounds (M = La-Gd) have been found to crystallize in the AlB2-type hexagonal structure. X-ray intensity data prove that the transition metal atoms replace part of the silicon atoms of the stoichiometric MSi2. The Mössbauer spectrum of LaSi1.6Fe0.4 shows the iron as closely divalent, with equal distribution of iron atoms between two symmetrically different sites. © 1969.
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页码:173 / &
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