STANDARD ENTHALPIES OF FORMATION OF SODIUM ALKOXIDES

被引：23

作者：

LEAL, JP

DEMATOS, AP

SIMOES, JAM

机构：

[1] INST CIENCIAS & ENGN NUCL, DEPT QUIM, NACL ENGN & TECHNOL IND LAB, P-2686 SACAVEM, PORTUGAL

[2] Univ Tecn Lisboa, DEPT ENGN QUIM, INST SUPER TECN, P-1096 LISBON, PORTUGAL

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 403卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)83081-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The standard enthalpies of formation of several crystalline sodium alkoxides, DETLA-H(f0)(NaOR, cr), have been determined by reaction-solution calorimetry. A linear correlation has been found between DELTA-H(f0)(NaOR, cr) and DELTA-H(f0)(ROH, 1/cr) for R = n-alkyl, enabling the prediction of data for other sodium alkoxides. The results were also used to derive the lattice energies and the thermochemical radii of the anions OR-.

引用

页码：1 / 10

页数：10

共 19 条

[1]

[Anonymous], 1982, SOME THERMODYNAMIC A

[2]

[Anonymous], 1982, J PHYS CHEM REF DATA

[3] ENTHALPY OF FORMATION OF ALKALIS METALS ETHYLATES [J].