TRIAURATED PHOSPHONIUM CATIONS [RP(AUPPH)3]+ AND THE ELECTRON-DEFICIENT, HYPERCOORDINATED PHOSPHONIUM DICATION [P(AUPPH3)5]2+

被引：66

作者：

SCHMIDBAUR, H

WEIDENHILLER, G

STEIGELMANN, O

机构：

[1] Anorganisch-Chemisches Institut, Technischen Universität München, Garching, W-8046

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 04期

关键词：

D O I：

10.1002/anie.199104331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The auration of arylphosphanes by reaction with [(Ph3PAu)3O]BF4 affords the triauriophosphonium salt 1, while reaction of P(SiMe3)3 with this oxonium salt yields 2, which has a hypercoordinated P center. The cation of 1 has an almost ideal tetrahedral geometry about the central P atom. The large radius of the P atom leads to large peripheral Au ... Au distances of 3.7 angstrom. R = omicron-tolyl.

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页码：433 / 435

页数：3

相关论文

共 43 条

[1] NOVEL GOLD CLUSTERS - PREPARATION, PROPERTIES, AND X-RAY STRUCTURE DETERMINATION OF SALTS OF OCTAKIS(TRIARYLPHOSPHINE)ENNEAGOLD, [AU9L8]X3 [J].

BELLON, PL ;

CARIATI, F ;

MANASSERO, M ;

NALDINI, L ;

SANSONI, M .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (22) :1423-+

[2] PREPARATION AND STRUCTURE OF HEXAKIS(TRIS PARA TOLYLPHOSPHINEGOLD) SALT OF TETRAPHENYLBORATE AND ELECTRONIC-STRUCTURE OF GOLD CLUSTER COMPOUNDS [J].

BELLON, PL ;

SANSONI, M ;

MANASSER.M ;

NALDINI, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (18) :1035-&

[3] AGOSTIC-TYPE GOLD LIGAND AND INCIPIENT MU-3-PPH2 COORDINATION IN THE AU2PT2P6 HAMMOCK SKELETON OF THE CLUSTER [AU2PT2(MU-PPH2)2(PPH3)4][PF6]2 [J].

BENDER, R ;

BRAUNSTEIN, P ;

DEDIEU, A ;

DUSAUSOY, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (07) :923-925

[4]

BENDER R, 1989, ANGEW CHEM, V101, P931

[5]

BISSINGER P, 1990, THESIS TU MUNCHEN

[6]

BRODBECK A, 1990, ACTA CRYSTALLOGR A, V46, pC232

[7]

BRODBECK A, 1990, THESIS U TUBINGEN

[8] GOLD(I) COMPLEXES DERIVED FROM SECONDARY PHOSPHINES - [(AU(MU-PR2))N], [(AUBR)2(MU-PPH2)]-, [AUX(PHR2)], AND [(AU(PHR2)N)]+ - CRYSTAL-STRUCTURE OF [AUBR(PHPH2)] [J].

DYSON, DB ;

PARISH, RV ;

MCAULIFFE, CA ;

PRITCHARD, RG ;

FIELDS, R ;

BEAGLEY, B .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (05) :907-914

[9] MOLECULAR-ORBITAL ANALYSIS OF THE BONDING IN LOW NUCLEARITY GOLD AND PLATINUM TERTIARY PHOSPHINE COMPLEXES AND THE DEVELOPMENT OF ISOLOBAL ANALOGIES FOR THE M(PR3) FRAGMENT [J].

EVANS, DG ;

MINGOS, DMP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 232 (02) :171-191

[10] ELECTRON-DEFICIENT BONDING AT PENTACOORDINATE NITROGEN [J].

GROHMANN, A ;

RIEDE, J ;

SCHMIDBAUR, H .

NATURE, 1990, 345 (6271) :140-142

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