DIASTEREOISOMERISM DUE TO NON-INVERTING NITROGEN ATOMS IN OXAZIRIDINES

被引：45

作者：

BOYD, DR

SPRATT, R

JERINA, DM

机构：

[1] Department of Chemistry, Queen's University, Belfast

[2] Laboratory of Chemistry, National Institute of Arthritis and Metabolic Diseases, National Institutes of Health, Bethesda

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 19期

关键词：

D O I：

10.1039/j39690002650

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stable oxaziridine diastereomers possessing a non-inverting nitrogen atom have been synthesised and photochemically interconverted. The relative stereochemistry of diastereomers has been deduced from spectral and chemical properties.

引用

页码：2650 / &

共 21 条

[1] ALLEN G, 1965, J CHEM SOC, P812
[2] ELECTROPHILIC SUBSTITUTION AT SATURATED CARBON.31. EFFECTS OF ATTACHED SECOND-ROW ELEMENTS ON RATES OF NITROGEN INVERSION IN AZIRIDINES
ANET, FAL
TREPKA, RD
CRAM, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (02) : 357 - &
[3] RETARDED RATE OF INVERSION IN AZIRIDINES
ATKINSON, RS
[J]. CHEMICAL COMMUNICATIONS, 1968, (12) : 676 - &
[4] NITRONES AND OXAZIRANS .3. PHOTOLYSIS OF 1-PYRROLINE 1-OXIDES AND THEIR RELATED OXAZIRANS
BAPAT, JB
BLACK, DSC
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1968, 21 (10) : 2507 - &
[5] AN APPRAISAL OF VALENCE-BOND STRUCTURES AND HYBRIDIZATION IN COMPOUNDS OF THE 1ST-ROW ELEMENTS
BENT, HA
[J]. CHEMICAL REVIEWS, 1961, 61 (03) : 275 - 311
[6] NUCLEAR MAGNETIC RESONANCE SPECTRA - NITROGEN INVERSION RATES OF N-SUBSTITUTED AZIRIDINES (ETHYLENIMINES)
BOTTINI, AT
ROBERTS, JD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (19) : 5203 - 5208
[7] BOYD DR, 1968, TETRAHEDRON LETT, P4561
[8] AZIRIDINES .11. NITROGEN INVERSION IN N-HALOAZIRIDINES
BROIS, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (02) : 506 - &
[9] BROIS SJ, 1958, TETRAHEDRON LETTERS, P5997
[10] THE PREPARATION AND PROPERTIES OF OXAZIRANES
EMMONS, WD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (21) : 5739 - 5754

← 1 2 3 →