CYCLOPENTADIENYL BIS(TRIARYLPHOSPHINE)COBALT(I)

被引：27

作者：

RINZE, PV

LORBERTH, J

NOTH, H

STUTTE, B

机构：

[1] Institut für Anorganische Chemie der Universität Marburg/Lahn, Gutenbergstr

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 19卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)85313-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of cyclopentadiene with L3CoHN2 or L3CoH3 [L = P(C6H5)3, P(p-ClC6H4)3] yields air sensitive π-cyclopentadienylbis(triarylphosphine)cobalt(I). During the reaction cyclopentadiene is hydrogenated to give cyclopentene and cyclopentane. CO replaces triphenylphosphine from π-C5H5 Co[P(C6H5)3]2 at normal pressure yielding the stable compound π-C5H5Co(CO)P(C6H5)3. © 1969.

引用

页码：399 / &

共 11 条

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