CYCLOPENTADIENYL BIS(TRIARYLPHOSPHINE)COBALT(I)

被引:27
作者
RINZE, PV
LORBERTH, J
NOTH, H
STUTTE, B
机构
[1] Institut für Anorganische Chemie der Universität Marburg/Lahn, Gutenbergstr
关键词
D O I
10.1016/S0022-328X(00)85313-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The interaction of cyclopentadiene with L3CoHN2 or L3CoH3 [L = P(C6H5)3, P(p-ClC6H4)3] yields air sensitive π-cyclopentadienylbis(triarylphosphine)cobalt(I). During the reaction cyclopentadiene is hydrogenated to give cyclopentene and cyclopentane. CO replaces triphenylphosphine from π-C5H5 Co[P(C6H5)3]2 at normal pressure yielding the stable compound π-C5H5Co(CO)P(C6H5)3. © 1969.
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页码:399 / &
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