LIQUID LIQUID VAPOR-PHASE EQUILIBRIUM BEHAVIOR OF CERTAIN BINARY NITROUS OXIDE+N-ALKANOL MIXTURES

被引：11

作者：

LAM, DH ^{[1
]}

JANGKAMOLKULCHAI, A ^{[1
]}

LUKS, KD ^{[1
]}

机构：

[1] UNIV TULSA,DEPT CHEM ENGN,TULSA,OK 74104

来源：

FLUID PHASE EQUILIBRIA | 1990年 / 60卷 / 1-2期

关键词：

Mixtures;

D O I：

10.1016/0378-3812(90)85046-D

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Liquid-liquid-vapor (LLV) phase equilibrium loci for the binary mixtures nitrous oxide + n-octanol, nitrous oxide + n-decanol and nitrous oxide + n-dodecanol were experimentally studied using a visual cell (stoichiometric) technique. The pressure, temperature, phase compositions and molar volumes of the two liquid phases are reported for all the mixtures. LLV locus end points are reported for all the nitrous oxide + n-alkanol mixtures from n-heptanol to n-hexadecanol; n-heptanol is the first member of the series to exhibit LLV immiscibility with nitrous oxide, while n-hexadecanol is the last. The mixture nitrous oxide + n-decanol exhibits two separate LLV loci. © 1990.

引用

页码：119 / 130

页数：12

共 17 条

[1] APPLICATION OF A GENERALIZED MULTIPROPERTY APPARATUS TO MEASURE PHASE-EQUILIBRIUM AND VAPOR-PHASE DENSITIES OF SUPERCRITICAL CARBON-DIOXIDE IN NORMAL-HEXADECANE SYSTEMS UP TO 26 MPA [J].