OXIDATION OF TRANS-STILBENE WITH PEROXYMONOPHOSPHORIC ACID

被引：20

作者：

OGATA, Y

TOMIZAWA, K

IKEDA, T

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku Nagoya

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 14期

关键词：

D O I：

10.1021/jo01328a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of frans-stilbene with peroxymonophosphoric acid (H3PO5) yielding ircms-stilbene oxide has been studied in various solvents at 25 °C. The rates in most solvents satisfy the equation : v = κ2[stilbene][H3PO5]. The solvents which have strong hydrogen bonding ability decrease the reaction rate. The reaction is catalyzed by H2SO4, the rate being correlated with the acidity function H0, which is not a general phenomenon for the reaction with peroxycarboxylic acid. The reaction carried out in acetonitrile afforded products derived from the further reactions of the epoxide. © 1979, American Chemical Society. All rights reserved.

引用

页码：2362 / 2364

页数：3

共 16 条

[1] REACTION OF CIS-STILBENE AND TRANS-STILBENE WITH PEROXYBENZOIC ACID IN THE PRESENCE OF TRICHLOROACETIC ACID [J].