LANTHANIDE(III) CATALYZED ALDOL REACTIONS OF GLYCERALDEHYDE ACETONIDE WITH KETENE SILYL ACETALS - CATALYTIC ASYMMETRIC ROUTE TO MONOSACCHARIDES

被引：21

作者：

MIKAMI, K

TERADA, M

NAKAI, T

机构：

[1] Department of Chemical Technology, Tokyo Institute of Technology, Meguro-ku, Tokyo

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(00)86145-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Pr-, Eu- and Ho(dppm)3 catalyzed aldol reactions of glyceraldehyde acetonide with ketene silyl acetals are described, where remarkably high anti-diastereofacial selection is achieved. Thus, the asymmetrc synthesis of 2-deoxy-D-ribonolactone and formal synthesis of 2-amino-2-deoxy-D-pentose by the lanthanide(III) catalyzed aldol reaction with ketene silyl acetals of acetate and alpha-chloroacetate, respectively are described.

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页码：993 / 996

页数：4

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