EFFECTS OF MAGNETIC-FIELD ON THE PERTURBATION BETWEEN THE B 1-PI AND C 3-SIGMA+ STATES OF NAK

被引：9

作者：

BABA, M ^{[1
]}

NISHIZAWA, K ^{[1
]}

YOSHIE, N ^{[1
]}

ISHIKAWA, K ^{[1
]}

KATO, H ^{[1
]}

机构：

[1] KOBE UNIV,FAC SCI,DEPT CHEM,NADA KU,KOBE 657,JAPAN

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 96卷 / 02期

关键词：

D O I：

10.1063/1.462115

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zeeman spectra of the strongly perturbed lines between the B (1)PI and c (3)SIGMA+ states of Nak were measured by the Doppler-free laser polarization spectroscopy. Magnetic field dependence of the Zeeman pattern was studied and the line shapes were found to change remarkably because of the mixing of the B (1)PI and c (3)SIGMA+ states. The patterns of Zeeman splitting were found to be different depending on whether the level was located on the high energy side or the low energy side of the interacting level. The observed Zeeman spectra were studied by taking account of the spin-orbit, hyperfine, and Zeeman interactions. The Zeeman spectroscopy is shown to be useful to analyze the perturbation between the excited states.

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收藏

页码：955 / 960

页数：6

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