ADSORPTION OF CHLORIDE IONS AT MERCURY/SOLUTION INTERFACE IN WATER-METHANOL MIXTURES

被引：23

作者：

MINC, S

JASTRZEB.J

ANDRZEJC.J

机构：

[1] Department of Physical Chemistry, University of Warsaw, Warsaw

来源：

ELECTROCHIMICA ACTA | 1969年 / 14卷 / 09期

关键词：

D O I：

10.1016/0013-4686(69)87004-0

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The specific adsorption of chloride ions on mercury has been investigated by capacitance and electrocapillary methods in three water-methanol mixtures, having various mole fractions of methanol. The surface concentration of Cl- ions is determined by graphical differentiation of the Parsons Φ-function, defined as the surface pressure of a specifically adsorbed component. As additional tests of specific adsorption in studied systems the slopes (∂q-'/∂qM)c, and ∂E+/∂(2RT/F) log a±]qM are calculated. © 1969.

引用

页码：821 / &

共 21 条

[1] ADSORPTION OF BUTYL, PHENYL AND NAPHTHYL COMPODS AT INTERFACE MERCURY-AQUEOUS ACID SOLUTION [J].