TRENDS ACROSS THE PERIODIC TABLE - A SCREENING OF THE GAS-PHASE CHEMISTRY OF D-BLOCK TRANSITION-METAL IONS WITH ISOCYANIDES

被引：32

作者：

ELLER, K ^{[1
]}

SCHWARZ, H ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 01期

关键词：

Mass Spectrometry / Metal ions; bare / Isocyanides / Bond activation; C–C and C–H / Ion–dipole complexes;

D O I：

10.1002/cber.19901230133

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By screening the reactions of alkyl isocyanides RNC with most of the d‐block transition metal ions several trends are uncovered that permit a deeper insight in the intrinsic properties of the metal ions. The ability of C – H activation, relative binding energies to alkenes and hydrogen isocyanide as well reactivity in general can be deduced from collisional activation of RNC/M+ complexes, using tandem mass spectrometry methodologies. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：201 / 208

页数：8

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