INVESTIGATION OF ORTHO-ACETOXYARYL RADICALS

被引：10

作者：

EVANOCHKO, WT ^{[1
]}

SHEVLIN, PB ^{[1
]}

机构：

[1] AUBURN UNIV,DEPT CHEM,AUBURN,AL 36830

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 24期

关键词：

D O I：

10.1021/jo01338a036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

o-Acetox:yphenyl radicals (4a) and 3-methyl-2-acetoxyphenyl radicals (4b) have been generated by decarboxylation of the corresponding benzoyloxy radicals. CIDNP studies and product analysis reveal no evidence for neighboring group participation by the acetoxy group or for acetoxy migration. The CIDNP investigations demonstrate that o-acetoxybenzoyloxy radicals decarboxylate slower than benzoyloxy radicals. © 1979, American Chemical Society. All rights reserved.

引用

页码：4426 / 4430

页数：5

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