POLAR PARAMETERS FOR RADICAL SUBSTITUENTS

被引：24

作者：

GIESE, B ^{[1
]}

MEHL, W ^{[1
]}

机构：

[1] TH DARMSTADT,INST ORGAN CHEM,W-6100 DARMSTADT,GERMANY

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 34期

关键词：

RADICAL ADDITION REACTIONS; POLAR EFFECTS; SUBSTITUENT PARAMETERS;

D O I：

10.1016/S0040-4039(00)92147-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polar substituent parameters for radicals (P(R)) are measured via the rate of radical addition reactions to substituted alkenes. Parameters are determined for OMe, Me, OAc and CO2R as substituents at the radical center.

引用

页码：4275 / 4278

页数：4

共 11 条

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