TRANSIENT INFRARED-SPECTROSCOPY AS A PROBE OF COORDINATIVELY UNSATURATED METAL-CARBONYLS IN THE GAS-PHASE

被引：71

作者：

WEITZ, E

机构：

[1] Department of Chemistry, Northwestern University, Evanston

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 44期

关键词：

D O I：

10.1021/j100095a005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Progress in the investigation of coordinatively unsaturated metal carbonyls by transient infrared spectroscopy is reviewed with an emphasis on gas phase studies. Typical current and possible future experimental methodologies are examined. The photophysics of production of coordinatively unsaturated metal carbonyls is discussed. Methods for the measurement of bond dissociation energies of transient species are reviewed, and the body of available data for coordinatively unsaturated metal carbonyls in the gas phase is presented. The current level of understanding of the factors that control the rate constants of ligand-metal carbonyl association reactions is discussed. Potential areas for future work are delineated.

引用

收藏

页码：11256 / 11264

页数：9

相关论文

共 104 条

[1] THE CHEMISTRY OF ATOMIC TRANSITION-METAL IONS - INSIGHT INTO FUNDAMENTAL-ASPECTS OF ORGANOMETALLIC CHEMISTRY [J].

ARMENTROUT, PB ;

BEAUCHAMP, JL .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (09) :315-321

[2] TIME-RESOLVED INFRARED SPECTRAL PHOTOGRAPHY - STUDY OF LASER-INITIATED EXPLOSIONS IN HN3 [J].

AVOURIS, P ;

BETHUNE, DS ;

LANKARD, JR ;

ORS, JA ;

SOROKIN, PP .

JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (04) :2304-2312

[3] SPECTROSCOPIC OBSERVATION OF A THERMAL C-H BOND INSERTION REACTION AT 5-K - INTRAMOLECULAR REARRANGEMENT OF FE(CO)3(ETA-2-C3H6) TO PRODUCE HFE(CO)3(ETA-3-C3H5) [J].

BARNHART, TM ;

MCMAHON, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :5434-5435

[4] TIME-RESOLVED INFRARED SPECTRAL PHOTOGRAPHY [J].

BETHUNE, DS ;

LANKARD, JR ;

SOROKIN, PP .

OPTICS LETTERS, 1979, 4 (04) :103-105

[5] BOND-DISSOCIATION ENERGIES AND KINETICS FOR THE REACTION OF W(CO)5 WITH THE UNLIKELY LIGANDS N2O AND CF2CL2 [J].

BOGDAN, PL ;

WELLS, JR ;

WEITZ, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (04) :1294-1299

[6] A TRANSIENT INFRARED-SPECTROSCOPY STUDY OF COORDINATIVELY UNSATURATED OSMIUM CARBONYL-COMPOUNDS [J].

BOGDAN, PL ;

WEITZ, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (02) :639-644

[7] A TRANSIENT INFRARED-SPECTROSCOPY STUDY OF COORDINATIVELY UNSATURATED RUTHENIUM CARBONYLS [J].

BOGDAN, PL ;

WEITZ, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) :3163-3167

[8] PULSED LASER PHOTOLYSIS OF CHROMIUM HEXACARBONYL IN THE GAS-PHASE [J].

BRECKENRIDGE, WH ;

STEWART, GM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) :364-367

[9] INTERACTION OF ALKANES WITH UNSATURATED METAL CENTERS .2. COMPLEXES OF ALKANES AND FLUOROALKANES WITH W(CO)5 IN THE GAS-PHASE [J].

BROWN, CE ;

ISHIKAWA, Y ;

HACKETT, PA ;

RAYNER, DM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) :2530-2536

[10]

BROWN CE, 1992, ACS SYM SER, V530, P177

← 1 2 3 4 5 6 7 8 9 10 →