IMMOBILIZATION, ELECTROCHEMISTRY, AND SURFACE INTERACTIONS OF TETRATHIAFULVALENE ON CHEMICALLY MODIFIED RUTHENIUM AND PLATINUM OXIDE ELECTRODES

被引：54

作者：

KUO, KN ^{[1
]}

MOSES, PR ^{[1
]}

LENHARD, JR ^{[1
]}

GREEN, DC ^{[1
]}

MURRAY, RW ^{[1
]}

机构：

[1] UNIV N CAROLINA,KENAN LABS CHEM,CHAPEL HILL,NC 27514

来源：

ANALYTICAL CHEMISTRY | 1979年 / 51卷 / 06期

关键词：

D O I：

10.1021/ac50042a038

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A monocarboxylic acid derivative of tetrathiafulvalene is Immobilized on RuO2 and PtO electrodes using alkylaminesilane chemistry. The cyclic voltammogram for oxidation of this molecular surface state to the radical cation involves larger surface activity non-Ideality parameters than does that for further oxidation to the dicatlon. Oxidation to the radical cation is facilitated by addition of chloride to the acetonitrile solvent medium. © 1979, American Chemical Society. All rights reserved.

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页码：745 / 748

页数：4

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共 21 条

[1] CYCLIC AND DIFFERENTIAL PULSE VOLTAMMETRIC BEHAVIOR OF REACTANTS CONFINED TO ELECTRODE SURFACE [J].

BROWN, AP ;

ANSON, FC .

ANALYTICAL CHEMISTRY, 1977, 49 (11) :1589-1595

[2] MODIFICATION OF A TIN OXIDE ELECTRODE BY ATTACHMENT OF IRON-SULFUR CLUSTERS [J].

BURT, RJ ;

LEIGH, GJ ;

PICKETT, CJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (22) :940-941

[3] VOLTAMMETRY AND POTENTIOMETRY OF TETRATHIAFULVALENE HALIDES [J].

CHAMBERS, JQ ;

GREEN, DC ;

KAUFMAN, FB ;

ENGLER, EM ;

SCOTT, BA ;

SCHUMAKER, RR .

ANALYTICAL CHEMISTRY, 1977, 49 (06) :802-806

[4] ELECTROCHEMISTRY OF SOME SURFACE-BONDED PYRAZOLINE DERIVATIVES [J].

DIAZ, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (17) :5838-5840

[5] 2ND HARMONIC AC VOLTAMMETRY OF SURFACE-BONDED PYRAZOLINES [J].

DIAZ, AF ;

KANAZAWA, KK .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1978, 86 (02) :441-444

[6] OXIDATIONS ON DSA AND CHIRALLY MODIFIED DSA AND SNO2 ELECTRODES [J].

FIRTH, BE ;

MILLER, LL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (25) :8272-8273

[7] ORGANO-MODIFIED METAL-OXIDE ELECTRODE .4. ANALYSIS OF COVALENTLY BOUND RHODAMINE-B PHOTOELECTRODE [J].

FUJIHIRA, M ;

OSA, T ;

HURSH, D ;

KUWANA, T .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1978, 88 (02) :285-288

[8] SYNTHETIC METHOD FOR PREPARATION OF MONOSUBSTITUTED TETRATHIAFULVALENES [J].

GREEN, DC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1977, (06) :161-162

[9] CHEMICALLY MODIFIED POLYMER ELECTRODES - SYNTHETIC APPROACH EMPLOYING POLY(METHACRYL CHLORIDE) ANCHORS [J].

ITAYA, K ;

BARD, AJ .

ANALYTICAL CHEMISTRY, 1978, 50 (11) :1487-1489

[10] ELECTROCHEMICAL PREPARATION AND CONTROL OF STOICHIOMETRY FOR DONOR-HALIDE SALTS - TTFX-N AND TSEFX-N [J].

KAUFMAN, FB ;

ENGLER, EM ;

GREEN, DC ;

CHAMBERS, JQ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (06) :1596-1597