INFRARED MATRIX-ISOLATION SPECTRA OF SOME PERFLUORO ORGANIC FREE-RADICALS .2. CF3O2

被引：42

作者：

BUTLER, R ^{[1
]}

SNELSON, A ^{[1
]}

机构：

[1] IIT,RES INST,CHICAGO,IL 60616

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 25期

关键词：

D O I：

10.1021/j100488a012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The radical CF3O2 has been formed by allowing CF3 radicals, produced by the pyrolysis of CF3I, to interact during condensation with an oxygen-doped argon matrix gas at 12 K. 16O2,18O2, and 16O18O isotope studies clearly demonstrated the presence of two symmetrically nonequivalent oxygen atoms in the molecule. Assuming Cs symmetry, 10 of the 12 possible fundamental vibrational modes were identified in the spectral range 2000-200 cm-1, and a tentative frequency assignment was made. © 1979 American Chemical Society.

引用

页码：3243 / 3248

页数：6

共 23 条

[1]

AMPHLETT JC, 1976, CAN J CHEM, V54, P8

[2] MATRIX INFARED STUDIES OF OF COMPOUNDS .I. OF RADICAL [J].