SYNTHESIS AND BINDING-PROPERTIES OF ETHYLBIPYRIDINIO-MODIFIED BETA-CYCLODEXTRIN

被引：13

作者：

DU, YQ ^{[1
]}

NAKAMURA, A ^{[1
]}

TODA, F ^{[1
]}

机构：

[1] TOKYO INST TECHNOL, FAC BIOSCI & BIOTECHNOL,DEPT BIOENGN,O-OKAYAMA, MEGURO KU, TOKYO 152, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 11期

关键词：

D O I：

10.1246/bcsj.63.3351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mono-6-deoxy-6-[4-(1-ethyl-4-pyridinio)-1-pyri-dinio]-β-cyclodextrin (3) was synthesized. The conformation and the binding properties of 3 with benzene derivatives were examined by induced circular dichroism (ICD) in aqueous solution. The conformation of 3 was confirmed to such equatorial inclusion as β-CDx capped by ethylviologen (C2V2+) group. Further, compound 3 showed stronger binding ability with these guests (1:1 complexes) compared with β-cyclodextrin (β-CDx). © 1990 The Chemical Society of Japan.

引用

页码：3351 / 3353

页数：3

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