CONFORMATIONAL-ANALYSIS OF T-5-METHYL-T-2-(TRIMETHYLSILYL)CYCLOHEXAN-R-OL AND ITS DERIVED ESTERS

被引:15
作者
KUAN, YL [1 ]
WHITE, JM [1 ]
机构
[1] UNIV MELBOURNE,DEPT CHEM,PARKVILLE,VIC 3052,AUSTRALIA
关键词
D O I
10.1039/c39940001195
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The existence of significant sigma-sigma* interactions involving the C-Si bonding orbital and the C-O antibonding orbital, results in a strong preference for the diaxial conformation forth esters 6a-m.
引用
收藏
页码:1195 / 1196
页数:2
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