BINDING OF DIHYDROXYBENZENES IN SYNTHETIC MOLECULAR CLEFTS

被引：40

作者：

SIJBESMA, RP ^{[1
]}

NOLTE, RJM ^{[1
]}

机构：

[1] CATHOLIC UNIV NIJMEGEN,DEPT ORGAN CHEM,TOERNOOIVELD,6525 ED NIJMEGEN,NETHERLANDS

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 09期

关键词：

D O I：

10.1021/jo00009a036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthetic molecular clefts of type 1 strongly bind dihydroxybenzenes in organic solvents. The association constants have values up to 3 x 10(5) M-1. The guests are sandwiched between the o-xylylene walls of the host and form hydrogen bonds with the receptor.

引用

页码：3122 / 3124

页数：3

共 18 条

[1]

[Anonymous], 2010, J AM CHEM SOC, DOI DOI 10.1021/ja102148f

[2] ON THE CIS-TRANS EQUILIBRIA IN ORTHO-HALOPHENOLS [J].

BAKER, AW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (14) :3598-3600

[3]

BIILMANN E, 1925, J CHEM SOC, V127, P205

[4] THERMODYNAMIC CONSTANTS OF COMPLEXES OF CROWN ETHERS AND UNCHARGED MOLECULES AND X-RAY STRUCTURE OF THE 18-CROWN-6.(CH3NO2)2 COMPLEX [J].

DEBOER, JAA ;

REINHOUDT, DN ;

HARKEMA, S ;

VANHUMMEL, GJ ;

DEJONG, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (15) :4073-4076

[5] A NEW WATER-SOLUBLE MACROCYCLIC HOST OF THE CYCLOPHANE TYPE - HOST GUEST COMPLEXATION WITH AROMATIC GUESTS IN AQUEOUS-SOLUTION AND ACCELERATION OF THE TRANSPORT OF ARENES THROUGH AN AQUEOUS PHASE [J].

DIEDERICH, F ;

DICK, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (26) :8024-8036

[6]

Diederich F., 1988, ANGEW CHEM, V100, P372

[7]

EBMEYER F, 1989, ANGEW CHEM, V100, P95

[8] DETERMINATION OF DISSOCIATION-CONSTANTS OF 1-1 COMPLEXES FROM NMR DATA - OPTIMIZATION OF THE EXPERIMENTAL SETUP BY STATISTICAL-ANALYSIS OF SIMULATED EXPERIMENTS [J].

GRANOT, J .

JOURNAL OF MAGNETIC RESONANCE, 1983, 55 (02) :216-224

[9] SYNTHESIS AND CHARACTERIZATION OF CROWNED 1,4-BENZOQUINONES AS IONOPHORE-DIENOPHILE (REDOX) COMBINED SYSTEMS - DOUBLE INTERACTION WITH CATECHOLAMINES AND TRYPTAMINE [J].

HAYAKAWA, K ;

KIDO, K ;

KANEMATSU, K .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (03) :511-519

[10]

KOHN M, 1950, J AM CHEM SOC, V73, P480

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