ASYMMETRIC INDUCTION STUDIES IN THE INTRAMOLECULAR PAUSON-KHAND CYCLIZATION OF 7-ALKOXY-1-HEPTEN-6-YNES

被引：50

作者：

POCH, M

VALENTI, E

MOYANO, A

PERICAS, MA

CASTRO, J

DENICOLA, A

GREENE, AE

机构：

[1] UNIV BARCELONA,DEPT QUIM ORGAN,MARTI & FRANQUES 1-11,E-08028 BARCELONA,SPAIN

[2] UNIV J FOURIER,LEDSS,F-38041 GRENOBLE,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(00)88530-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric induction has been achieved in the intramolecular Pauson-Khand reaction of 7-alkoxy-1-hepten-6-ynes derived from chiral alcohols. The stereochemical outcome of the reaction can be explained by the intermediacy of a cis-cobaltabicyclooctane.

引用

页码：7505 / 7508

页数：4

共 29 条

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