A NEW SYNTHESIS OF ALKYL-N,N-DINITRAMINES BY DIRECT NITRATION OF ISOCYANATES

被引：31

作者：

BOTTARO, JC ^{[1
]}

PENWELL, PE ^{[1
]}

SCHMITT, RJ ^{[1
]}

机构：

[1] SRI INT,ORGAN CHEM PROGRAM,333 RAVENSWOOD AVE,MENLO PK,CA 94025

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 07期

关键词：

D O I：

10.1080/00397919108019779

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile conversion of aliphatic isocyanates to N,N-dinitramines has been developed. An aliphatic isocyanate is treated with a mixture of nitronium fluoroborate and nitric acid in acetonitrile giving fair yields and simplifing the existing synthesis.

引用

页码：945 / 949

页数：5