CALCULATION OF TRANSITION-STATE STRUCTURES AND KINETIC ISOTOPE EFFECTS IN THE CLAISEN REARRANGEMENT OF ALLYL VINYL ETHER AND CHORISMIC ACID

被引：12

作者：

DAVIDSON, MM

HILLIER, IH

机构：

[1] Chemistry Department, University of Manchester, Manchester

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 225卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(94)00595-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The calculated transition state for the Claisen rearrangement of chorismic acid is considerably more dissociative than that for allyl vinyl ether. The predicted kinetic isotope effects for the two reactions are in accord with experimental measurements.

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收藏

页码：293 / 296

页数：4

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