CHLORINE-FREE IRON-RUTHENIUM CATALYST FOR THE WATER-GAS SHIFT REACTION

被引：25

作者：

BASINSKA, A

DOMKA, F

机构：

[1] Department of Kinetics and Catalysis, Faculty of Chemistry, Adam Mickiewicz University, Poznań, 60-780

来源：

CATALYSIS LETTERS | 1993年 / 22卷 / 04期

关键词：

RUTHENIUM CATALYSTS; ALLOY CATALYSTS; WATER GAS SHIFT REACTIONS;

D O I：

10.1007/BF00807240

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present results of studies on the activity of chlorine-free iron-ruthenium catalysts in the water-gas shift reaction. The catalysts were prepared by impregnation of calcination products of alpha-, beta-, gamma-, delta-iron oxide-hydroxides with Ru3(CO)12. For two iron oxides (from alpha- and delta-FeOOH) the reaction rate constants are considerably higher than those of reactions with other catalysts based on RuCl3. Among the catalysts used, those obtained by impregnation of delta-FeOOH calcination product with Ru3(CO)12 appeared to be the most active.

引用

页码：327 / 331

页数：5

共 17 条

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