OXIDATIVE GENERATION OF THIOALKYL CATIONS FROM 2-TRIBUTYLSTANNYL-1,3-DITHIANES AND 1-(TRIBUTYLSTANNYL)ALKYL SULFIDES AND THEIR REACTIONS WITH OLEFINIC NUCLEOPHILES

被引：35

作者：

NARASAKA, K

ARAI, N

OKAUCHI, T

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 10期

关键词：

D O I：

10.1246/bcsj.66.2995

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-'Tributylstannyl-1,3-dithianes and 1- (tributylstannyl)alkyl sulfides are oxidized with ammonium hexanitratocerate(IV) or ferrocenium hexafluorophosphate to generate their cation radicals, which dissociate into the carbocations and tributylstannyl radical. The carbocations thus generated react with olefinic nucleophiles to afford the corresponding addition products in good yield.

引用

页码：2995 / 3003

页数：9

共 40 条

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