COMPLEXATION OF SELENO-CYSTEAMINE, SELENO-CYSTEINE AND SELENO-ETHANOIC ACID WITH GOLD(I) THIOMALATE

被引：10

作者：

ISAB, AA

机构：

[1] Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 06期

关键词：

D O I：

10.1007/BF00980410

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Seleno-cysteamine, seleno-cysteine and seleno-ethanoic acid react with aurothiomalate in aqueous solution to give [Au(selenoate)(2)](-) complexes. The C-13-n.m.r. chemical shift differences between thiolates and their analogous selenoates complexes with gold(I), as [Au(thiolate)(2)](-) and [Au(selenoate)(2)](-), are compared and the [Au(Se-cysteine)(2)](-) complex was found to be the most stable.

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页码：595 / 598

页数：4

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