DIRECT OXIDATIVE CONVERSION OF GRAPHITE INTO EXFOLIATED GRAPHITES - THE KINETIC-MODEL, PRODUCTS, MECHANISM

被引：2

作者：

LYUBCHIK, SB

KUCHERENKO, VA

YAROSHENKO, AP

机构：

[1] Institute of Physical Organic & Coal Chemistry, Ukrainian Academy of Sciences

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1994年 / 244卷

关键词：

D O I：

10.1080/10587259408050090

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The process of thermally initiated synthesis of acceptor type graphite intercalation compounds (GICs) and the products of their thermolysis, i.e. exfoliated graphite (EG) has been considered within the scope of common kinetic model. Analysis of the data available in literature and results of present work indicate that in some cases direct oxidative conversion (DOC) of graphite into EG without specified GIC formation can be realized. DOC-process has been discovered for powder ''graphite - M(2+)(NO3)(2)(-)'' mixtures at the temperature greater than or equal to 300-degrees C. The conditions for DOC-process realization are considered.

引用

页码：107 / 113

页数：7

共 10 条

[1] HETEROGENEOUS-HOMOGENEOUS DECOMPOSITION OF HNO3 [J].