SYNTHESIS OF 3-ISOCYANO-NIDO-7,8-DICARBAUNDECABORATE SALTS AND THEIR USE AS NEW ISONITRILE LIGANDS IN TRANSITION-METAL COMPLEXES

被引：6

作者：

ZAKHARKIN, LI

OLSHEVSKAYA, VA

SULAIMANKULOVA, DD

机构：

[1] A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 08期

关键词：

3-ISOCYANO-O-CARBORANES, 3-ISOCYANO-NIDO-7,8-DICARBAUNDECABORATES; CHROMIUM; MOLYBDENUM; TUNGSTEN AND IRON COMPLEXES;

D O I：

10.1007/BF00699940

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The treatment of 3-isocyano-o-carboranes with an alkali solution in alcohol results in the regioselective splitting out of a boron atom from position 6 of the o-carborane nucleus to give 3-isocyano-nido-7,8-dicarbaundecaborate salts, in which the isonitrile group is attached to the boron atom of the nido-polyhedron anion. 3-Isocyano-nido-7,8-dicarbaundecaborate salts are new isonitrile ligands in transition-metal complexes. Complexes with chromium, molybdenum, tungsten, and iron compounds have been obtained.

引用

页码：1395 / 1397

页数：3

共 7 条

[1] NEW OLEFIN DICARBONYLISONITRILEIRON(0) COMPLEXES [J].