EVIDENCE FOR FORMATION OF CARBANIONS IN CLEAVAGE OF CARBON-SILICON BONDS BY METHANOLIC SODIUM METHOXIDE - SOME LARGE KINETIC ISOTOPE EFFECTS FOR REACTIONS OF CARBANIONS WITH METHANOL

被引:29
作者
EABORN, C
WALTON, DRM
SECONI, G
机构
[1] UNIV SUSSEX,SCH MOLEC SCI,BRIGHTON BN1 9QJ,SUSSEX,ENGLAND
[2] CNR,COMPOSTI CARBONIO CONTENENTI ETEROATOMI LORO APPL LAB,I-40064 OZZANO EMILIA,ITALY
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1976年 / 15期
关键词
D O I
10.1039/p29760001857
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
引用
收藏
页码:1857 / 1861
页数:5
相关论文
共 26 条
[1]   SOLVENT ISOTOPE-EFFECTS IN CLEAVAGE OF BENZYLTRIMETHYL-SILANES AND BENZYLTRIMETHYL-STANNANES BY ALKALI [J].
ALEXANDER, R ;
ASOMANIN.WA ;
EABORN, C ;
JENKINS, ID ;
WALTON, DRM .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1974, (05) :490-494
[2]   AROMATIC REACTIVITY .55. SOLVENT ISOTOPE-EFFECTS IN BASE CLEAVAGE OF ARYLTRIMETHYLSTANNANES IN METHANOL - EVIDENCE FOR ELECTROPHILIC ASSISTANCE BY SOLVENT [J].
ALEXANDER, R ;
ASOMANIN.WA ;
EABORN, C ;
JENKINS, ID ;
WALTON, DRM .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1974, (03) :304-308
[3]   ISOTOPE EFFECT IN THE DECOMPOSITION OF GRIGNARD COMPOUNDS BY ORDINARY PHENOL AND A STERICALLY HINDERED PHENOL [J].
ASSARSSON, LO .
ACTA CHEMICA SCANDINAVICA, 1958, 12 (07) :1545-1547
[4]   SUBMICROSECOND FORMATION AND OBSERVATION OF REACTIVE CARBANIONS [J].
BOCKRATH, B ;
DORFMAN, LM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (18) :5708-5715
[5]   ORGANOSILICON COMPOUNDS .33. ADDITIONAL SUBSTITUENT EFFECTS IN ALKALI CLEAVAGE OF BENZYLTRIMETHYLSILANES [J].
BOTT, RW ;
EABORN, C ;
RUSHTON, BM .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1965, 3 (06) :448-&
[6]   ALKALI-CLEAVAGE OF SOME CARBON-SILICON, -GERMANIUM, AND -TIN BONDS [J].
BOTT, RW ;
SWADDLE, TW ;
EABORN, C .
JOURNAL OF THE CHEMICAL SOCIETY, 1963, (APR) :2342-&
[7]  
CHERNYSHEV EA, 1960, B ACAD SCI USSR, P1323
[8]   DETERMINATION OF STEREOCHEMISTRY OF SI-C BOND-CLEAVAGE VIA ASYMMETRIC SYNTHESIS AT LEVEL OF SILICON ATOM [J].
CORRIU, RJP ;
HENNER, BJL .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 105 (03) :303-310
[9]  
CREEKS JE, 1975, PROTON TRANSFER REAC, pCH6
[10]   AROMATIC REACTIVITY .61. REACTIVITIES AND SOLVENT ISOTOPE EFFECTS IN BASE CLEAVAGE OF TRIORGANO-SILICON, TRIORGANO-GERMANIUM, AND TRIORGANO-TIN GROUPS FROM FURAN, THIOPHENE, BENZOFURAN, AND BENZOTHIOPHEN RINGS [J].
EABORN, C ;
SECONI, G .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1976, (08) :925-930