HIGH-RESOLUTION MASS SPECTROMETRY .6. A HYDROGEN REARRANGEMENT IN MASS SPECTRA OF PYRAZOLE OXIMES

被引：12

作者：

FINAR, IL

MILLARD, BJ

机构：

[1] Dept. of Chemistry, Northern Polytechnic

[2] School of Pharmacy, London W.C.1, 29/39, Brunswick Sq.

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 18期

关键词：

D O I：

10.1039/j39690002497

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mass spectra of a number of syn- and anti-1-phenylpyrazol-4-yl oximes have been studied. syn- and anti-Pairs where available gave identical mass spectra; although no Beckmann rearrangement occurred, a transfer of the oximino-hydrogen to the pyrazole nucleus with concommittant fission of the side chain was shown to take place.

引用

页码：2497 / &