MASS SPECTRA OF SOME ACYCLIC ALPHA,BETA-UNSATURATED ALDEHYDES, KETONES AND ESTERS

被引:23
作者
BOWLES, AJ
BRITTAIN, EF
GEORGE, WO
机构
[1] Department of Chemistry, Kingston College of Technology, Kingston Upon Thames, Surrey
来源
ORGANIC MASS SPECTROMETRY | 1969年 / 2卷 / 08期
关键词
D O I
10.1002/oms.1210020807
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The mass spectra of a series of aliphatic acyclic α,β‐unsturated aldehydes, ketones and ester have been examined. The spectra do not show evidence for McLafferty rearrangements, alkoxyl migration or for fragmentations which are dependent upon the s‐trans or s‐cis conformations of the compounds. There is some evidence for cis‐trans isomerism about the double bond. Copyright © 1969 John Wiley & Sons, Ltd.
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页码:809 / &
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